1 March 2018 12MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.2 Blackbody Radiation: The Ultraviolet Catastrophe
•Lord Rayleigh and James Jeans started by considering
the radiation inside a cavity of absolute temperature to
be a series of standing EM waves (Fig. 2.7).
•The condition for standing waves in such a cavity is
that the path length from wall to wall, whatever the
direction, must be a whole number of half-wavelengths,
so that a node occurs at each reflecting surface.
•The number of independent standing waves in
the frequency interval per unit volume in the cavity
turned out to be
•Because each standing wave in a cavity originates in an
oscillating electric charge in the cavity wall, two
degrees of freedom are associated with the wave and it
should have an average energy of
Figure 2.7 Standing waves that
have nodes at the walls, which
restricts their possible
wavelengths. Shown are three
possible wavelengths when the
distance between opposite walls
is L
(Density of standing waves in cavity)
(Classical average energy per standing wave)