Chapter 2
Particle Properties of Waves
2 Particle Properties of Waves
1 March 2018 2MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2 Particle Properties of Waves
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Particle ==> Mechanics
Waves ==> Optics
Carry energy and momentum from one place to another.
Microscopic world of atoms and molecules, electrons and nuclei
in this world, there are neither particles nor waves in our sense.
We regard electrons as particles because they possess charge and mass
and behave according to the laws of particle mechanics.
However, it is just as correct to interpret a moving electron as a wave as
it is to interpret it as a particle.
We regard electromagnetic waves as waves because under suitable
circumstances they exhibit diffraction, interference, and polarization.
Similarly, we shall see that under other circumstances electromagnetic
waves behave as though they consist of streams of particles.
The wave-particle duality is central to an understanding of modern
physics.
2.1 Electromagnetic Waves
1 March 2018 4MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
Coupled electric and magnetic oscillations that move with the speed of
light and exhibit typical wave behavior.
Accelerated electric charges generate linked electric and magnetic
disturbances that can travel indefinitely through space.
If the charges oscillate periodically, the disturbances are waves
whose electric and magnetic components are perpendicular to each
other and to the direction of propagation, as in Fig. 2.1
Figure 2.1 The electric and magnetic fields in an electromagnetic wave vary together. The fields are
perpendicular to each other and to the direction of propagation of the wave.
James Clerk Maxwell
(18311879)
Maxwell was able to show that the speed c of electromagnetic (EM)
waves in free space is given by
where ε
0
the electric permittivity of free space and µ
0
is its magnetic
permeability. This is the same as the speed of light waves.
1 March 2018 5MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.1 Electromagnetic Waves
Many features of EM waves interaction with matter depend upon their
frequencies.
Light waves, which are EM waves the eye responds to, span only a
brief frequency interval,
Figure 2.2 The spectrum of electromagnetic radiation.
from about 4.3x10
14
Hz for red
light
to about 7.5x10
14
Hz for violet
light.
1 March 2018 6MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.1 Electromagnetic Waves: Principle of superposition
When two or more waves of the same nature travel past a point at the
same time, the instantaneous amplitude there is the sum of the
instantaneous amplitudes of the individual waves.
Amplitude of a water wave is the height of the water surface relative
to its normal level.
Amplitude of a sound wave is the change in pressure relative to the
normal pressure.
Amplitude of a light wave (E=cB) can be taken as either E or B.
Usually E is used, since its interactions with matter give rise to
nearly all common optical effects.
1 March 2018 7MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.1 Electromagnetic Waves: Interference
When two or more trains of light waves meet in a region, they interfere
to produce a new wave there whose instantaneous amplitude is the sum
of those of the original waves.
Constructive interference refers to the reinforcement of waves with
the same phase to produce a greater amplitude. Fig 2.3a
Destructive interference refers to the partial or complete
cancellation of waves whose phases differ. Fig 2.3b
If the original waves have different frequencies, the result will be a
mixture of constructive and destructive interference.
Figure 2.3 (a) In constructive interference, superposed waves in phase reinforce each other. (b) In
destructive interference, waves out of phase partially or completely cancel each other.
1 March 2018 8MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.1 Electromagnetic Waves:Young’s Double Slit Experiment
Interference of light waves Fig. 2.4.
From each slit secondary waves spread out as though originating at the slit. Diffraction.
At those places on the screen where the path lengths from the two slits differ by an odd
number of half wavelengths, λ (1/2, 3/2, 5/2, …), destructive interference occurs and a
dark line is the result.
At those places where the path lengths are equal or differ by a whole number of
wavelengths, λ (1, 2, 3, …), constructive interference occurs and a bright line is the
result.
At intermediate places the interference is only partial, so the light intensity on the
screen varies gradually between the bright and dark lines.
Thomas Young
1773-1829
Figure 2.4 Origin of the interference pattern in Young’s experiment.
1 March 2018 9MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.1 Electromagnetic Waves
Interference and diffraction are found only in waves.
If light consisted of a stream of classical particles, the entire screen
would be dark.
Thus, Young’s experiment is proof that light consists of waves.
1 March 2018 10MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.2 Blackbody Radiation
Until the end of the nineteenth century the nature of light seemed settled
forever.
Attempts to understand the origin of the radiation emitted by bodies
of matter.
All objects radiate energy continuously whatever their temperatures.
Which frequencies predominate depends on the temperature.
At room temperature, most of the radiation is in the infrared part of
the spectrum and hence is invisible.
Figure 2.5 A hole in the wall of a hollow object is
an excellent approximation of a blackbody.
Any radiation striking the hole enters the
cavity, where it is trapped by reflection back
and forth until it is absorbed.
The cavity walls are constantly emitting and
absorbing radiation, and it is in the properties
of this radiation (blackbody radiation).
Sample blackbody radiation simply by
inspecting what emerges from the hole in the
cavity.
1 March 2018 11MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.2 Blackbody Radiation
A blackbody radiates more when it is hot than
when it is cold, and the spectrum of a hot
blackbody has its peak at a higher frequency
than the peak in the spectrum of a cooler one.
The spectrum of blackbody radiation is
shown in Fig. 2.6 for two temperatures.
Why does the blackbody spectrum have the
shape shown in Fig. 2.6?
Only the quantum theory of light can explain
its origin.
Figure 2.6 Blackbody spectra. The spectral
distribution of energy in the radiation depends
only on the temperature of the body. The higher
the temperature, the greater the amount of
radiation an”d the higher the frequency at which
the maximum emission occurs.
1 March 2018 12MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.2 Blackbody Radiation: The Ultraviolet Catastrophe
Lord Rayleigh and James Jeans started by considering
the radiation inside a cavity of absolute temperature to
be a series of standing EM waves (Fig. 2.7).
The condition for standing waves in such a cavity is
that the path length from wall to wall, whatever the
direction, must be a whole number of half-wavelengths,
so that a node occurs at each reflecting surface.
The number of independent standing waves in
the frequency interval per unit volume in the cavity
turned out to be
Because each standing wave in a cavity originates in an
oscillating electric charge in the cavity wall, two
degrees of freedom are associated with the wave and it
should have an average energy of
Figure 2.7 Standing waves that
have nodes at the walls, which
restricts their possible
wavelengths. Shown are three
possible wavelengths when the
distance between opposite walls
is L
(Density of standing waves in cavity)
(Classical average energy per standing wave)
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2.2 Blackbody Radiation: The Ultraviolet Catastrophe
The total energy per unit volume in the cavity in the frequency interval
is therefore
The Rayleigh-Jeans formulae, contains everything that classical physics
can say about the spectrum of blackbody radiation.
Figure 2.8 Comparison of the Rayleigh-Jeans formula
for the spectrum of the radiation from a blackbody at
1500 K with the observed spectrum.
In reality, of course, the energy density (and
radiation rate) falls to 0 as frequency goes
to infinity (see Fig. 2.8).
This discrepancy became known as the
ultraviolet catastrophe of classical
physics.
Where did Rayleigh and Jeans go wrong?
(Rayleigh-Jeans formula)
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2.2 Blackbody Radiation: The Ultraviolet Catastrophe
This failure of classical physics led Planck to the discovery
that radiation is emitted in quanta whose energy is .
Considered to mark the start of modern physics.
At high frequencies and at low frequencies Planck’s formula
becomes Rayleigh-Jeans formula.
(Planck’s constant)
(Planck radiation formula)
Max Planck
(18581947)
Nobel Prize in
Physics in 1918
The oscillators in the cavity walls could not have a continuous
distribution of possible energies ε but must have only the specific
energies
An oscillator emits radiation of frequency ν when it drops from one
energy state to the next lower one, and it jumps to the next higher state
when it absorbs radiation of frequency ν.
Each discrete bundle of energy hν is called a quantum (plural quanta)
from the Latin for “how much.”
(Oscillator energies)
1 March 2018 15MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.2 Blackbody Radiation: The Ultraviolet Catastrophe
With oscillator energies limited to nhν, the average energy per oscillator
in the cavity walls
(Actual average energy per standing wave)
Example 2.1
Assume that a certain 660-Hz tuning fork can be considered as a harmonic
oscillator whose vibrational energy is 0.04 J. Compare the energy quanta of
this tuning fork with those of an atomic oscillator that emits and absorbs
orange light whose frequency is 5.00x10
14
Hz.
1 March 2018 16MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.3 Photoelectric Effect
The energies of electrons liberated by light depend on the frequency of
the light.
Electrons emitted when the frequency of the light was sufficiently high.
This phenomenon is known as the photoelectric effect and the emitted
electrons are called photoelectrons.
Some of the photoelectrons that emerge
from this surface have enough energy to
reach the cathode despite its negative
polarity (the measured current).
When the voltage is increased to a certain
value V
0
, no more photoelectrons arrive (the
current dropping to zero).
Maximum photoelectron kinetic energy.
Figure 2.9 Experimental observation of the photoelectric
effect..
1 March 2018 17MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.3 Photoelectric Effect
Three experimental findings;
1.There is no time interval between the arrival of light at a metal surface
and the emission of photoelectrons.
However, because the energy in an EM wave is supposed to be
spread across the wavefronts, a period of time should elapse
before an individual electron accumulates enough energy (several
eV) to leave the metal.
Figure 2.10 Photoelectron current is proportional to
light intensity I for all retarding voltages. The
stopping potential V
0
, which corresponds to the
maximum photoelectron energy, is the same for all
intensities of light of the same frequency.
2.A bright light yields more photoelectrons than a
dim one of the same frequency, but the electron
energies remain the same (Fig. 2.10).
The EM theory of light, on the contrary,
predicts that the more intense the light, the
greater the energies of the electrons.
1 March 2018 18MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.3 Photoelectric Effect
3.The higher the frequency of the light, the more energy the
photoelectrons have (Fig. 2.11).
At frequencies below a certain critical frequency ν
0
, which is
characteristic of each particular metal, no electrons are emitted.
Above ν
0
the photoelectrons range in energy from 0 to a maximum
value that increases linearly with increasing frequency (Fig.2.12).
This observation, also, cannot be explained by the em theory of light.
Figure 2.12 Maximum photoelectron kinetic energy KE
max
versus
frequency of incident light for three
metal surfaces.
Figure 2.11 The stopping potential V
0
, and hence the maximum
photoelectron energy, depends on the frequency of the light. When the
retarding potential is V=0, the photoelectron current is the same for light
of a given intensity regardless of its frequency.
1 March 2018 19MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.3 Photoelectric Effect; Quantum Theory of Light
In 1905, Einstein realized that the photoelectric effect
could be understood if the energy in light is not spread
out over wavefronts but is concentrated in small packets,
or photons.
•Each photon of light of frequency ν has the energy hν,
the same as Planck’s quantum energy
Albert Einstein
1879 1955
Nobel Prize in
Physics in 1921
Energy was not only given to EM waves in separate quanta but was
also carried by the waves in separate quanta.
The three experimental observations listed above follow directly from
Einstein’s hypothesis.
1.Because EM wave energy is concentrated in photons and not spread out,
there should be no delay in the emission of photoelectrons.
2.All photons of frequency have the same energy, so changing the intensity
of a monochromatic light beam will change the number of photoelectrons
but not their energies.
3.The higher the frequency ν, the greater the photon energy hν and so the
more energy the photoelectrons have.
1 March 2018 20MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.3 Photoelectric Effect; Quantum Theory of Light
There must be a minimum energy φ for an electron to escape from a
particular metal surface (Fig 2.13).
This energy is called the work function of the metal, and is related to ν
0
by the formula
The greater the work function of a metal, the more energy is needed
for an electron to leave its surface, and the higher the critical frequency
for photoelectric emission to occur.
(Photoelectric effect)
(Work function)
where hν is the photon energy, KE
max
is the
maximum photoelectron energy (which is
proportional to the stopping potential), and φ is
the minimum energy needed for an electron to
leave the metal.
Figure 2.13 If the energy
0
(the work function of the
surface) is needed to remove an electron from a metal
surface, the maximum electron kinetic energy will be -
0
when light of frequency is directed at the surface.
In terms of electron volts, the formula
E=hν for photon energy becomes
(Photon energy)
1 March 2018 21MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.3 Photoelectric Effect; Quantum Theory of Light
Example 2.2
Ultraviolet light of wavelength 350 nm and intensity 1.00 W/m
2
is directed at a
potassium surface.
(a) Find the maximum KE of the photoelectrons.
(b) If 0.50 percent of the incident photons produce photoelectrons, how many are
emitted per second if the potassium surface has an area of 1.00 cm
2
?
1 March 2018 22MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.4 What is Light?
Both wave and particle.
The wave theory of light explains diffraction and interference, for
which the quantum theory cannot account.
According to the wave theory, light waves leave a source with their
energy spread out continuously through the wave pattern.
The quantum theory explains the photoelectric effect, for which the
wave theory cannot account.
According to the quantum theory, light consists of individual
photons, each small enough to be absorbed by a single electron.
Think of light as having a dual character.
The wave theory and the quantum theory complement each other.
Either theory by itself is only part of the story and can explain only
certain effects.
1 March 2018 23MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.4 What is Light?
In double-slit interference pattern on a screen.
When it passes through the slits, light is behaving
as a wave does.
When it strikes the screen, light is behaving as a
particle does.
Apparently light travels as a wave but absorbs and
gives off energy as a series of particles.
In the wave model, the light intensity at a place on the
screen depends on E
2
, the average over a complete
cycle of the square of the instantaneous magnitude E of
the EM wave’s electric field.
In the particle model, this intensity depends on Nhν,
where N is the number of photons per second per unit
area that reach the same place on the screen.
Figure 2.14 (a) The wave
theory of light explains
diffraction and interference,
which the quantum theory
cannot account for.
(b) The quantum theory
explains the photoelectric
effect, which the wave
theory cannot account for.
1 March 2018 24MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.4 X-Rays: X-rays are EM waves
High-energy photons.
The photoelectric effect provides convincing evidence that
photons of light can transfer energy to electrons.
Is the inverse process also possible? That is, can part or all of
the kinetic energy of a moving electron be converted into a
photon?
In 1895 Wilhelm Roentgen found that a highly penetrating
radiation of unknown nature is produced when fast electrons
impinge on matter.
The faster the original electrons, the more penetrating the
resulting x-rays.
The greater the number of electrons, the greater the intensity
of the x-ray beam.
Electromagnetic theory predicts that an accelerated electric
charge will radiate EM waves.
Acceleration: Rapidly moving electron suddenly
brought to rest.
Wilhelm Konrad
Roentgen
(18451923)
First Nobel Prize
in Physics in 1902
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2.4 X-Rays: Bremsstrahlung (“braking radiation”)
In 1912 a method was devised for measuring the wavelengths of x-rays.
The spacing between adjacent lines on a diffraction grating must be of
the same order of magnitude as the wavelength of the light.
Max von Laue realized that the wavelengths suggested for x-rays were
comparable to the spacing between adjacent atoms in crystals.
He therefore proposed that crystals be used to diffract x-rays, with their
regular lattices acting as a kind of three-dimensional grating (Fig. 2.15).
Figure 2.15 An x-ray tube. The higher the accelerating
voltage V, the faster the electrons and the shorter the
wavelengths of the x-rays.
Classical electromagnetic theory predicts
bremsstrahlung when electrons are
accelerated, which accounts in general for
the x-rays produced by an x-ray tube.
Figures 2.16 and 2.17 show the x-ray spectra
that result when tungsten and molybdenum
targets are bombarded by electrons at
several different accelerating potentials.
1 March 2018 26MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.4 X-Rays
Figure 2.16 X-ray spectra of tungsten at
various accelerating potentials.
Figure 2.17 X-ray spectra of tungsten and
molybdenum at 35 kV accelerating potential.
The curves exhibit two
features electromagnetic
theory cannot explain:
1.In the case of molybdenum,
intensity peaks occur that
indicate the enhanced
production of x-rays at
certain wavelengths. These
peaks occur at specific
wavelengths for each target
material and originate in rearrangements of the electron structures of the target atoms
after having been disturbed by the bombarding electrons. The presence of x-rays of
specific wavelengths, a decidedly non-classical effect, in addition to a continuous x-ray
spectrum.
2.The x-rays produced at a given accelerating potential V vary in wavelength, but none
has a wavelength shorter than a certain value λ
min
. Increasing V decreases λ
min
. Duane
and Hunt found experimentally that
(X-ray production)
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2.4 X-Rays: Inverse photoelectric effect
The second observation fits in with the quantum theory of radiation.
Most of the electrons that strike the target undergo numerous glancing collisions,
with their energy going simply into heat.
A few electrons lose most or all of their energy in single collisions with
target atoms. This is the energy that becomes x-rays.
Since work functions are only a few electron-volts (eVs) whereas the
accelerating potentials in x-ray tubes are typically tens or hundreds of
thousands of volts, we can ignore the work function.
Iinterpret the short wavelength limit of X-ray production Equation as
corresponding to the case where the entire kinetic energy KE=Ve of a
bombarding electron is given up to a single photon of energy
max
.
(Duane-Hunt formula of X-ray production Equation)
1 March 2018 28MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.4 X-Rays
Example 2.3
Find the shortest wavelength present in the radiation from an x-ray machine whose
accelerating potential is 50.000 V.
1 March 2018 29MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.6 X-Ray Diffraction: How x-ray wavelengths can be determined?
A crystal consists of a regular array of atoms, each of which can
scatter EM waves.
The mechanism of scattering is straightforward.
An atom in a constant electric field becomes polarized since its negatively
charged electrons and positively charged nucleus experience forces in opposite
directions.
So, the result is a distorted charge distribution equivalent to an electric dipole.
In the presence of the alternating electric field of an EM wave of frequency ν,
the polarization changes back and forth with the same frequency ν.
An oscillating electric dipole is thus created at the expense of some of the
energy of the incoming wave.
The oscillating dipole in turn radiates EM waves of frequency ν, and
these secondary waves go out in all directions except along the
dipole axis. (see Fig. 2.18).
1 March 2018 30MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.6 X-Ray Diffraction: Bragg planes
Figure 2.18 The scattering of electromagnetic
radiation by a group of atoms. Incident
plane waves are reemitted as spherical waves.
A monochromatic beam of x-rays that falls
upon a crystal will be scattered in all directions
inside it.
However, owing to the regular arrangement of
the atoms, in certain directions the scattered
waves will constructively interfere with one
another while in others they will destructively .
The atoms in a crystal may be thought of as defining families
of parallel planes with each family having a characteristic
separation between its component planes.
This analysis was suggested in 1913 by W. L Bragg, in honor
of whom the above planes are called Bragg planes.
William
Lawrence Bragg
(18901971)
Nobel Prize in
Physics in 1915
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2.6 X-Ray Diffraction: Conditions
Figure 2.20 X-ray scattering from a cubic
crystal.
The conditions that must be fulfilled for
radiation scattered by crystal atoms to
undergo constructive interference may be
obtained from a diagram like that in Fig.2.20.
A beam containing x-rays of wavelength λ is
incident upon a crystal at an angle with a
family of Bragg planes whose spacing is d.
The beam goes past atom A in the first plane and atom B in the next,
and each of them scatters part of the beam in random directions.
Constructive interference takes place only between those scattered rays
that are parallel and whose paths differ by exactly λ, 2λ, 3λ, and so on.
That is, the path difference must be nλ, where n is an integer.
1.The first condition on I and II is that their common scattering angle be equal to the
angle of incidence of the original beam.
2.The second condition is that
since ray II must travel the distance 2d sin farther than ray I. The integer n is the
order of the scattered beam.
1 March 2018 32MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.6 X-Ray Diffraction: Experimental Demonstration
Figure 2.21 X-ray ray spectrometer.
If the spacing d between adjacent Bragg planes in the crystal is known,
the x-ray wavelength λ may be calculated.
1 March 2018 33MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.7 Compton Effect
Figure 2.22 (a) The scattering of a photon by an electron is called the Compton effect. Energy and momentum are conserved in such an
event, and as a result the scattered photon has less energy (longer wavelength) than the incident photon. (b) Vector diagram of the momenta
and their components of the incident and scattered photons and the scattered electron.
Further confirmation of the photon model.
According to the quantum theory of light, photons behave like particles
except for their lack of rest mass.
Figure 2.22 shows a collision: an x-ray photon strikes an electron
(assumed to be initially at rest in the laboratory coordinate system).
The momentum of a massless particle is related to its energy by the
formula
1 March 2018 34MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.7 Compton Effect: Conservations
We can think of the photon as losing an amount of energy in the
collision that is the same as the kinetic energy KE gained by the
electron.
•Since the energy of a photon is hν, its momentum is
(Photon momentum)
In the collision momentum must be conserved in each of two mutually
perpendicular directions.
(In the
original
photon
direction) (2)
(In
perpendicular
to original
photon
direction) (3)
The angle is that between the
directions of the initial and
scattered photons, and is that
between the directions of the
initial photon and the recoil
electron.
(1)
From Eqns. (1-3) we can find a formula that relates ….
1 March 2018 35MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.7 Compton Effect: Compton wavelength
From Eqns. (1-3) we can find a formula that relates the wavelength
difference between initial and scattered photons with the angle
between their directions, both of which are readily measurable
quantities (unlike the energy and momentum of the recoil electron).
(Compton effect)
Compton effect equation was derived by Arthur H. Compton
in the early 1920s, and the phenomenon it describes is known
as the Compton effect.
It constitutes very strong evidence in support of the quantum
theory of radiation.
Change in wavelength is independent of the wavelength of
the incident photon.
The quantity
Arthur Holly
Compton
(18921962)
Nobel Prize in
Physics in 1927
(Compton wavelength)
is called the Compton wavelength of the scattering particle.
For an electron λ
C
=2.426x10
-12
m, which is 2.426 pm. (1 pm=1 picometer=10
-12
m)
1 March 2018 36MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.7 Compton Effect: Experimental Demonstration
From Compton effect equation, we note that the greatest wavelength
change possible corresponds to =180°.
Changes of this magnitude or less are readily observable only in x-rays.
The Compton effect is the main reasoning that which x-rays lose energy
when they pass through matter.
The experimental demonstration of the Compton effect is straightforward.
As in Fig. 2.23, a beam of x-rays of a
single, known wavelength is directed
at a target, and the wavelengths of the
scattered x-rays are determined at
various angles.
The results are shown in Fig. 2.24.
Figure 2.23 Experimental demonstration of the Compton effect.
1 March 2018 37MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.7 Compton Effect
Figure 2.24 Experimental confirmation of Compton scattering. The greater the scattering angle, the greater the wavelength change, in accord
with Compton effect equation.
1 March 2018 38MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.7 Compton Effect
Example 2.4
X-rays of wavelength 10.0 pm are scattered from a target. (a) Find the wavelength of
the x-rays scattered through 45°. (b) Find the maximum wavelength present in the
scattered x-rays. (c) Find the maximum kinetic energy of the recoil electrons.
1 March 2018 39MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2 Solved Problems
1. (a) What are the energy and momentum of a photon of red light of
wavelength 650 nm? (b) What is the wavelength of a photon of
energy 2.40 eV?
1 March 2018 40MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2 Solved Problems
2. The maximum wavelength for photoelectric emission in tungsten is
230 nm. What wavelength of light must be used in order for
electrons with a maximum energy of 1.5 eV to be ejected?
1 March 2018 41MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2 Solved Problems
3. The work function for tungsten metal is 4.52 eV. (a) What is the
cutoff wavelength λ
c
for tungsten? (b) What is the maximum kinetic
energy of the electrons when radiation of wavelength 198 nm is
used? (c) What is the stopping potential in this case?
1 March 2018 42MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2 Solved Problems
4. A laser beam with an intensity of 120W/m
2
(roughly that of a small
helium-neon laser) is incident on a surface of sodium. It takes a
minimum energy of 2.3 eV to release an electron from sodium (the
work function φ of sodium). Assuming the electron to be confined
to an area of radius equal to that of a sodium atom (0.10 nm), how
long will it take for the surface to absorb enough energy to release
an electron?
1 March 2018 43MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2 Solved Problems
5. Electrons are accelerated in television tubes through potential
differences of about 10 kV. Find the highest frequency of the
electromagnetic waves emitted when these electrons strike the
screen of the tube. What kind of waves are these?
1 March 2018 44MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2 Solved Problems
6. A single crystal of table salt (NaCl) is irradiated with a beam of X
rays of wavelength 0.250 nm, and the first Bragg reflection is
observed at an angle of 26.3
o
. What is the atomic spacing of NaCl?
1 March 2018 45MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2 Solved Problems
7. X rays of wavelength 0.2400 nm are Compton-scattered, and the
scattered beam is observed at an angle of 60.0 relative to the
incident beam. Find: (a) the wavelength of the scattered X rays, (b)
the energy of the scattered X-ray photons, and (c) the kinetic energy
of the scattered electrons
1 March 2018 46MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2 Solved Problems
8. Gamma rays of energy 0.662 MeV are Compton scattered.
a. What is the energy of the scattered photon observed at a
scattering angle of 60
o
?
b. What is the kinetic energy of the scattered electrons?
1 March 2018 47MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
Chapter 2 Particle Properties of Waves
Additional Materials
1 March 2018 48MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.8 Pair Production
1.Energy into matter.
2.As we have seen, in a collision a photon can give
an electron all of its energy (the photoelectric
effect) or only part (the Compton effect).
3.It is also possible for a photon to materialize into
an electron and a positron, which is a positively
charged electron. In this process, called pair
production, electromagnetic energy is converted
into matter.
Figure 2.25 In the process of pair production, a photon of
sufficient energy materializes into an electron and a positron.
No conservation principles are violated when an electron-positron pair
is created near an atomic nucleus (Fig. 2.25).
The sum of the charges of the electron (q=-e) and of the positron
(q=e) is zero, as is the charge of the photon
The total energy, including rest energy, of the electron and positron
equals the photon energy
Linear momentum is conserved with the help of the nucleus, which
carries away enough photon momentum for the process to occur.
1 March 2018 49MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.8 Pair Production
The rest energy mc
2
of an electron or positron is 0.51 MeV, hence pair
production requires a photon energy of at least 1.02 MeV.
Any additional photon energy becomes kinetic energy of the electron
and positron. The corresponding maximum photon wavelength is 1.2
pm. Electromagnetic waves with such wavelengths are called gamma
rays, symbol γ, and are found in nature as one of the emissions from
radioactive nuclei and in cosmic rays.
The inverse of pair production occurs when a positron is near an
electron and the two come together under the influence of their
opposite electric charges. Both particles vanish simultaneously, with the
lost mass becoming energy in the form of two gamma-ray photons:
The total mass of the positron and electron is equivalent to
1.02 MeV, and each photon has an energy hν of 0.51 MeV
plus half the kinetic energy of the particles relative to their
center of mass.
The directions of the photons are such as to conserve both energy and linear
momentum, and no nucleus or other particle is needed for this pair annihilation
to take place.
(Pair annihilation)
1 March 2018 50MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.8 Pair Production: Photon Absorption
The three chief ways in which photons of light, x-rays, and gamma rays
interact with matter are summarized in Fig. 2.27.
In all cases photon energy is transferred to
electrons which in turn lose energy to atoms
in the absorbing material.
At low photon energies, the photoelectric
effect is the main mechanism of energy loss.
The importance of the photoelectric effect
decreases with increasing energy, to be
succeeded by Compton scattering.
Figure 2.27 X- and gamma rays interact with matter
chiefly through the photoelectric effect, Compton
scattering, and pair production. Pair production requires a
photon energy of at least 1.02 MeV.
1 March 2018 51MSE 228 Engineering Quantum Mechanics © Dr.Cem Özdoğan
2.8 Pair Production: Photon Absorption
The greater the atomic number of the
absorber, the higher the energy at which
the photoelectric effect remains
significant.
In the lighter elements, Compton
scattering becomes dominant at photon
energies of a few tens of keV,
whereas in the heavier ones this does not
happen until photon energies of nearly 1
MeV are reached (Fig. 2.28).
Figure 2.28 The relative probabilities of the
photoelectric effect, Compton scattering, and pair
production as functions of energy in carbon (a light
element) and lead (a heavy element).